Originally Posted by
BladeRunner001
+1 on this...
As for the scientific evidence:
Heat and alkalinity allow for breaking up the hydrogen bonding that occurs in the Keratin proteins of hair. These proteins confer hair the structural stability it possesses for normal function. Breaking up what holds hair together (think glue) will make it easier to cut them.
As for oil...The main reason you remove "old oil" is because it is the site where dead cells, bacteria, skin secretions (toxins and such) end up in. This hardens throughout the day, plugging up the pores (through which your hair is sticking out). Plugged up pores mean less "breathing" of the follicle and moisture retention of your skin/hair. Exogenous oil is not used to soften the hair, per se...it provides lubrication. Oil bonds to hair's protein (H-bonding and hydrophobic - or oil loving part - interactions) and is used to effectively allow the creation of a barrier that helps your skin better retain it's moisture...well, I can see why people think that is softens hair :). Removal of oil does not harden hair directly...it leads to effective breathing of underlying skin cells and moisture loss, which causes dryness and "cracking".
Now, what cremes/soaps do is provide you with 1) oil (fats etc...), 2) glycerin (moisture retention), and 3) alkalinity (H-bond breaking). All these factors and heat play a role in softening up hair and getting it prepped for cutting.
IMO, the reason that people report having closer than normal shaves with cold water is because in the presence of cold water, the skin around the hair follicle retracts/shrinks, effectively exposing more of the hair to cutting...after shaving in cold water, your skin will return to your normal temperature of 37ºC, thus engulfing more of the hair...this leads to a closer shave. Personally, I prefer a warm lather than a cold one.
I hope this helps, :)