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Yes use the DMT first and make sure they are lapped flat. You can do this by taking a ruler and making an X (with a pencil) from top left to bottom right then top right to bottom left. Use water then...

Since the Naniwa lower grit hones are pretty inexpensive I'd add a 3000 for those picky razors that need that little extra between 1000 and 5000.

I agree that the Naniwa Super Stones are certainly the best for a new user just learning to hone. The grits Jimmy mentioned should serve you well. I would also advise you to purchase a DMT steel to...