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I usually rinse with cold water, splash on witch hazel, wait for it to dry, and then splash on the aftershave.
As you get better, there won't be as much burn.

Welcome to SRP!
I'll second the Van Der Hagen as a starter soap. They make a starter kit with soap, bowl, and mug for around $12 at a lot of drugs stores and wal marts, etc. It's actually a pretty...