Originally Posted by
straightman
Jim,
Vinegar is a carboxylic acid (OH). But I don't recall my chemistry well enough to predict the reaction resultant from mixing bleach (a.k.a. NaOCl or sodium hypochlorite) with a carboxylic acid. Uhhh, le'me see...OH + NaOCl > NaCl + H2O? Or, OH + NaOCl > NaOH + Cl2 + H2O.
How'd I do? Maybe someone on this board that's a little more up on their chemistry than I can verify which of these reactions is correct (maybe neither). Either way it looks to me like the possible by products of these reactions would be corrosive to steel...NaCl is salt and NaOH is sodium hydroxide (a.k.a. lye). And if the second reaction is correct one of the by products could be chlorine gas which is both corrosive and deadly. As I said, I'm a little rusty on my chemistry and I would welcome anyone who can set me straight on this.
Tom