I always shave in the morning. I have a hot shower and then brush my teeth while the waters heating.
Then I soak the soap and brush, and strop the razor up while the soap softens and then lather up and go to it!
Its a really great way to start the day, and I actually get up a little earlier just to make sure I have time for a proper shave. Days that start with a DE shave are never as good lol..! :)