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Thread: Celluloid in modern razors
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12-01-2009, 12:14 AM #11
People usually describe the smell as vinegar.
No matter how many men you kill you can't kill your successor-Emperor Nero
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12-01-2009, 07:45 AM #12
thebigspendur,
The acidic, vinegary smell is from traces of nitric acid, either from the original manufacture of the celluloid, or from its break down.
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Best regards
Russ
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12-01-2009, 05:44 PM #13
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Thanked: 3164Cellulose acetate breaks down to give a vinegar smell (sometimes also a bit like ammonia) - it was once called the "vinegar syndrome." It may also stretch, shrink and flex and exude the plasticiser, leaving an oily deposit, as well as triggering a chemical reaction in nearby articles made of cellulose acetate.
Cellulose nitrate is worse: the breakdown products are strongly acidic: this causes metals to rust and as it is a strong oxidising agent it can also cause spontaneous combustion (early formulations). To counter this, camphor was added - hence the camphor smell.
Two types of celluloid - two different smells!
Who knows how many more varieties there are?
Regards,
Neil