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My post shave is:
cold water splash
cold alum block all over
let alum dry for a bit. I clean my brush and mug now
rinse off with after shave
pat dry
then apply post shave moisturizer I use...

Ive been using an alum block on my face for the last 3 months. I haven't had a day or razor burn since. I dont see it harming your head after a shave. Im a barber and do quite a few of them. ...